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Dr. Mohammed Al-Hashimi

Dr. Mohammed Al-Hashimi

Research Assistant Professor

Office Number:
Office Phone: +974.4423.0185


​The research in Al-Hashimi's group focuses on the synthesis of organic polymers in particular the "design and synthesis of organic semiconductor materials" for a range of optoelectronic applications, including field effect transistors, photovoltaic devices, light emitting diodes and sensors. This has made enormous scientific and commercial progress over the last 10 years, mainly driven by the potential of applications such as light-emitting diodes (OLEDS) for display and large area lighting, field effect transistors (OFETs) for flexible backplanes and e-paper and solar cells (OPV) for large area energy generation.

Other topics of interest center on: 

  • The development of well-defined novel polymeric materials for Ring Opening Metathesis Polymerisation (ROMP) and Ring closing Metathesis (RCM).
  • Synthesis of recoverable, reusable homogeneous and heterogeneous catalysts.

Education

  • MSci Pharmaceutical Chemistry Queen Mary University of London, UK (2003)
  • Ph.D Queen Mary University of London, UK (2007) 

Experience

  • ​Postdoctoral Fellowship Imperial College London, UK (2008-2011) 
  • Postdoctoral Fellowship Texas A&M University at Qatar (2011-2012)
  • Visiting Assistant Professor of Chemistry Qatar University (2012-2013)
  • Associate Research Scientist Texas A&M University at Qatar (2013-2014) 
  • Research Scientist Texas A&M University at Qatar (2014-2016)
  • Research Assistant Professor (2016-Present)

Awards

  • ​"Best Research Presentation Award in the Energy and Environment Pillar" Qatar Foundation 2016.
  • "Research Fellow Excellence Award" Texas A&M University at Qatar 2015.
  • "Lefevre Prize" at Queen Mary University of London 2005.
  • "ASPICC Conference Prize" at University College London 2004.
  • "Donald C. Bradley Prize" at Queen Mary University of London 2003.

Publications

1. Bithiazole an Intriguing Electron Deficient Building for Plastic Electronic Applications; H. -Lih Su, H. Bronstein, T. J. Marks, B. C. Schroeder, M. Al-Hashimi,* Macromolecular Rapid Commun. 2017, Just acceptedDOI: 10.1002/marc.201600610/full

2. Fully Conjugated Ladder Polymers; J. Lee, A. J. Kalin, T. Yuan, M. Al-Hashimi, L. Fang; Chem. Sci., 2017, 8, 2503-2521 DOI: 10.1039/C7SC00154A

Selected to be on the front cover of issue 4Chem. Sci., 2017, 8, 2467-2467, DOI: 10.1039/C7SC90018J

3. Mapping the electrocatalytic activity of MoS2 across its amorphous to crystalline transition; Y-Hyuk Choi, J. Cho, A. M. Lunsford, M. Al-Hashimi, L. Fang, S. Banerjee; J. Mater. Chem. A., 2017, 5, 5129-5141 DOI: 10.1039/C6TA10316B, Paper

4. Synthesis of low band gap polymers based on pyrrolo[3,​2 d:4,​5-​d']​bisthiazole (PBTz) and thienylenevinylene (TV) for organic thin-​film transistors (OTFTs); D. Patra, J. Lee, J. Lee, D. N. Sredojevic, A. JP White, H. S. Bazzi, E. Brothers, M. Heeney, L. Fang, M.-Han Yoon, M. Al-Hashimi; J. Mater. Chem. C., 2017, 5 (9), 2247-2258. DOI: 10.1039/C6TC04763G

“Selected to be on the back cover of issue 9J. Mater. Chem. C.,2017, 5, 2476-2476, DOI:10.1039/C7TC90039B.

5. Indolo-​naphthyridine-​6,​13-​dione thiophene (INDT) building block for conjugated polymer electronics: Molecular origin of ultra-​high n type mobility; K. J Fallon, N. Wijeyasinghe, E. F Manley, S. D. Dimitrov, S. A. Yousaf, R. S Ashraf, W. Duffy, A. A. Y. Guilbert, D. M. E. Freeman, M. Al-Hashimi, J. Nelson, J. R. Durrant, X. C. Lin, I. McCulloch, T. J. Marks, T. Clarke, T. D Anthopoulos, H. Bronstein; Chem. Mater., 2016, 28 (22), 8366-8378. DOI:10.1021/acs.chemmater.6b03671

6. Doping of Large Ionization Potential Indenopyrazine Polymers via Lewis Acid complexation with tris(pentafluorophenyl)borane: A Simple Method for Improving the Performance of Organic Thin-Film Transistors; Y. Han, G. Barnes, Y. Lin, J. Martín, M. Al-Hashimi, T. D. Anthopoulos, Martin Heeney; Chem. Mater., 2016, 28, 8016-8024. DOI: 10.1021/acs.chemmater.6b03761.

7. Convenient protocols for Mizoroki–Heck reactions of aromatic bromides and polybromides with fluorous alkenes of the formula H2C[double bond, length as m dash]CH(CF2)n−1CF3 (n = 8, 10); H-Lih Su, J. Balogh, M. Al Hashimi, D. G. Seapy, H. S. Bazzi, J. A. Gladysz; Org. Biomol. Chem., 2016, 14, 10058-10069. DOI: 10.1039/C6OB01980C

8. Synthesis and catalytic activity of supported acenaphthoimidazolylidene N-heterocyclic carbene ruthenium complex for ring closing metathesis (RCM) and ring opening metathesis polymerization (ROMP); A. R. Hlil, S. Moncho , R. Tuba, K. Elsaid, G. Szarka, E. N. Brothers, R. H. Grubbs, M. Al-Hashimi, H. S. Bazzi; J. Catal., 2016, 344, 100–107. DOI.org/10.1016/j.jcat.2016.08.019.

9. Synthesis of Recyclable Tire Additives via Equilibrium Ring-Opening Metathesis Polymerization; R. Tuba, J. Balogh, A. Hlil, M. Barłóg, M. Al-Hashimi, H. S. Bazzi. ACS Sustainable Chemistry & Engineering, 2016, 4, 6090-6094. DOI: 10.1021/acssuschemeng.6b01496.

10. Conjugated Copolymers of Vinylene Flanked Naphthalene Diimide; Z. Fei, Y. Han, J. Martin, F. H. Scholes, M. Al Hashimi, N. Stingelin, T. D. Anthopoulos, M. Heeney. Macromolecules, 2016, 49, 6384-6393. DOI: 10.1021/acs.macromol.6b01423.

11. An in Situ Sulfidation Approach for the Integration of MoS2 Nanosheets on Carbon Fiber Paper and the Modulation of Its Electrocatalytic Activity by Interfacing with nC60; Yun-H. Choi, J. Lee, A. Parija, J. Cho, S. V. Verkhoturov, M. Al-Hashimi, L. Fang, S. Baner; ACS Catalysis, 2016, 6, 6246-6254; DOI:org/10.1021/acscatal.6b01942.

12. Ruthenium-Catalyzed Metathesis of Conjugated Polyenes; Á. Balla, M. Al-Hashimi, A. Hlil, H. S. Bazzi, R. Tuba. ChemCatChem, 2016, 8, 2865-2875; DOI:10.1002/cctc.201600479.

13. Thermodynamic synthesis of solution processable ladder polymers; J. Lee, B. B. Rajeeva, T. Yuan, Z. Guo, M. Al-Hashimi, Y. Zheng and L. Fang, Chem. Sci., 2016, 7, 881-889, DOI: 10.1039/C5SC02385H

Selected to be on the front cover of issue 2Chem. Sci., 2016, 7, 813-813, DOI:10.1039/C6SC90007K

14. Influence of the heteroatom on the optoelectronic properties and transistor performance of soluble thiophene-, selenophene- and tellurophene–vinylene copolymers; M. Al-Hashimi, Y. Han, J. Smith, H. S. Bazzi, S. E. Watkins, T. D Anthopoulos, M. Heeney, Chem. Sci., 2016, 7, 1093-1099, DOI: 10.1039/C5SC03501E

15. Synthesis of Polypentenamer and Poly(Vinyl Alcohol) Using Phase Separable PIB Second Generation Hoveyda-Grubbs Catalyst; M. Al-Hashimi, R. Tuba, H. S. Bazzi, R. H. Grubbs, ChemCatChem., 2016, 8, 228-233, DOI/10.1002/cctc.201500930

16. A novel nature-inspired conjugated polymer for high performance transistors and solar cells; K. J. Fallon, N. Y. Gross, R. S. Ashraf, D. Freeman, R. G. Palgrave, M. Al-Hashimi, T. J. Marks, I. McCulloch, T. D. Anthopoulos and H. Bronstein, Macromolecules, 2015, 48, 5148–5154. DOI/10.1021/acs.macromol.5b00542

17. One-Pot Synthesis of Polyvinyl Alcohol (PVA) Copolymers via Ruthenium Catalyzed Equilibrium Ring-Opening Metathesis Polymerization of Hydroxyl Functionalized Cyclopentene; R. Tuba, M. Al-Hashimi, H. S. Bazzi, R. H. Grubbs, Macromolecules, 2014, 47, 8190–8195. DOI: 10.1021/ma501976v

18. Ring-Opening Metathesis Polymerization using Polyisobutylene Supported Grubbs Second- Generation Catalyst; M. Al-Hashimi, M. A. Baker, K. El-Said, D. E. Bergbreiter, H. S. Bazzi, RSC Advances, 2014, 4, 43766-43771. DOI:10.1039/C4RA08046G 

19. Phase-separable PIB polymerization catalysts; M. Al-Hashimi, H. S. Bazzi, D. E. Bergbreiter. Abstracts of Papers of the American Chemical Society, 2014, 247. ISSN: 69SHSU.

20. Controlled synthesis of conjugated random copolymers in a droplet-based microreactor; J. H. Bannock, M. Al-Hashimi, S. H. Krishnadasan, J. J. M. Halls, M. Heeney and J. C. de Mello, Mater. Horiz. 2014, 1, 214-218. 10.1039/C3MH00066D

21. Lower ruthenium leaching using PIB-supported metathesis catalyst; H. S. Bazzi, M. Al- Hashimi, D. E. Bergbreiter. Abstracts of Papers of the American Chemical Society, 2013, 245. ISSN: 0065-7727.

22. Activated Singlet Exciton Fission in a Semiconducting Polymer; A. J. Musser, M. Al-Hashimi, M. Maiuri, D. Brida, M. Heeney, G. Cerullo, R. Friend, J. Clark, J. Am. Chem. Soc., 2013, 135 (34) 12747-12754. DOI:/abs/10.1021/ja405427j

23. Fullerene-Polymer Miscibility: A Metric for Screening New Materials for High Performance Organic Solar Cells; N. Treat, A. Varotto, C. Takacs, M. Al-Hashimi, M. Heeney, A. Heeger, F. Wudl, C. Hawker, J. Am. Chem. Soc., 2012, 134 (38), 15869-1587. DOI:.org/10.1021/ja305875u

24. Effects of a Heavy Atom on Thin Film Morphology of Conjugated Polymer: Fullerene Photovoltaic Blends; W. C. Tsoi, D. T. James, E. B. Domingo, J. S. Kim, M. Al-Hashimi, C. E. Murphy, N. Stingelin, M. Heeney, Ji-Seon Kim, ACS Nano., 2012DOI: 10.1021/nn304024g

25. A Phase Separable Second Generation Hoveyda-Grubbs Catalyst for Ring-Opening Metathesis Polymerization; M. Al-Hashimi, C. Hongfa, B. George, H. S. Bazzi, and D. E. Bergbreiter, J. Polym Sci Part A: Polym. Chem., 2012, 50, 3954–3959. DOI: 10.1002/pola.26206.

26. Fused pyrrolo[3,2-d:4,5-d] bisthiazole-ontaining polymers for using in high-performance organic bulk heterojunction solar cells; R. Xia, M. Al-Hashimi, W. C. Tsoi, M. Heeney, D. D. C. Bradley, J. Nelson. Sol. Energy Mater. Sol. Cell., 2012, 96, 112-116. DOI:10.1016/j.solmat.2011.09.027

27. Hybrid Polymer Solar Cells from Zinc Oxide and Poly (3-hexylselenophene); S. D. Oosterhout, M. Wienk, M. Al-Hashimi, M. Heeney and R. A. J. Janssen. J. Phys. Chem. C., 2011, 115, 18901–18908. DOI:10.1021/jp206005q

28. Effects of Thermal Annealing Upon the Nanomorphology of Poly(3-hexylselenophene)- PCBM Blends; S. Lilliu, T. Agostinelli, E. Verploegen, E. Pires, M. Hampton, M. Al- Hashimi, M. J. Heeney, M. F. Toney, J. Nelson, J. E. Macdonald. Macromol. Rapid Commun., 2011, 32, 1454– 1460. DOI/10.1002/marc.201100330

29. Synthesis, characterisation and field effect transistor properties of regioregular poly(3-alkyl- 2,5 selenylenevinylene); M. Al-Hashimi, M. A. Baklar, F. Colleaux, S. E. Watkins, T. D. Anthopoulos, N. Stingelin and M. Heeney. Macromolecules, 2011, 44, 5194-5199. DOI:10.1021/ma200910a

30.Influence of Ion Induced Local Coulomb Field and Polarity on Charge Generation and Efficiency in Poly (3 Hexylthiophene) Based Solid-State Dye-Sensitized Solar Cells; A. Abrusci, R. Sai, S. Kumar, M. Al-Hashimi, M. Heeney, A. Petrozza and H. J. Snaith. Adv. Funct. Mater., 2011, 21, 2571-2579. DOI/10.1002/adfm.201100048

31. Facile Infiltration of Semiconducting Polymer into Mesoporous Electrodes for Hybrid Solar Cells; A. Abrusci, I-K. Ding, M. Al-Hashimi, T. Segal-Peretz, M.D. McGehee, M. Heeney, G.L. Frey, and H.J. Snaith. Energy & Environmental Science, 2011, 4, 3051-3058. DOI:19.1039/E1EE01135A

32. Synthesis and Characterization of Fused Pyrrolo[3,2-d:4,5-d′]bisthiazole-Containing Polymers; M. Al-Hashimi, J. G. Labram, S. Watkins, M. Motevalli, T. D. Anthopoulos and M. Heeney. Org. Lett., 2010, 12, 5478-5481. DOI:10.1021/ol102344m

33. Structural and optoelectronic effects of chalcogen atom manipulation on low bandgap polymers. M. Heeney, M. Al-Hashimi, I. McCulloch, W. Zhang and R. Hamilton; Abstracts of Papers of the American Chemical Society, 2009, 238. ISSN:0065-7727

34. Dithio palladium modified silicas-New heterogeneous catalysts for Suzuki cross-coupling reactions; M. Al-Hashimi, A. Qazi, A. C. Sullivan and J. R. H. Wilson, J. Mol. Catal. A. Chem., 2007, 278, 164-168. DOI:10.1016/J.Molcata.2007.07.050

35. Palladium ethylthioglycolate modified silica- a new heterogeneous catalyst for Suzuki and Heck coupling reactions; M. Al-Hashimi, A. C. Sullivan and J. R. H. Wilson, J. Mol. Catal. A. Chem., 2007, 273, 298-302. DOI:10.1016/J.Molcata.2007.04.012

36. Selective oxidation of sulfides to sulfoxides using a silica immobilised vanadyl alkyl phosphonate catalyst; M. Al-Hashimi, E. Fisset, A.C. Sullivan and J. R. H. Wilson, Tetrahedron Lett., 2006, 47, 8107-8019. DOI:10.1016/j.tetlet.2006.09.065

37. Selective oxidations of sulfides to sulfoxides using immobilized cerium alkyl Phosphonate; M. Al-Hashimi, G. Roy, J. R. H. Wilson and A. C. Sullivan, Tetrahedron Lett., 2005, 46, 4365-4368. DOI:10.1016/j.tetlet.2005.04.079

38. Rare and unexpected coordination of copper (II) to a tertiary amide in a macrocyclic Ligand; K.F.Sibbons, M. Al Hashimi, M. Motevalli, J. Wolowska and M. Watkinson, Dalton. Trans., 2004, 3163-3165. DOI:10.1039/B410525G